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- SurfaTech Corporation
- 2170 Luke Edwards Road
- Dacula, Ga. 30019
- (678)
468-9315 (678) 442-9624 Fax
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- Esters are a class of
materials that contain two alkyl groups. They conform to the following
structure;
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R-C(O)-OR’
- These materials are commonly
used in personal care products as oil phases. While water insoluble,
they are more polar than hydrocarbon based oils. These materials are
used as emollients, lubricants and sun care additives. Esters generally
have a surface tension of around 32 dynes/cm2.
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- When esters are made from di-hydroxy compounds, tri-hydroxy compounds or
tetra hydroxy compounds they are referred to as complex esters. Examples
are:
- Diester
R-C(O)-O-(CH2CH2O)4C(O)-R
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CosmoSurftm E-DT
- INCI: PEG-4 dicocoate and
stearyl dimethicone
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CAS: 69278-77-9
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EINECS: 273-950-9
- Triester CH3-CH2-C-(CH2OC(O)-R)3
- CosmoSurftm
E-T8
- INCI Names:
Trimethylolpropane Tricaprate/tricarpylate
- CAS No.: 68130-52-9
- EINECS No.: 268-591-1
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- Tetraester C-(CH2OC(O)-R)4
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CosmoSurf TME-P8
- INCI: Pentaerythrityl
tertacaprate/tetracarpylate
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CAS: 68441-68-9
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EINECS: 270-474-3
- Many other complex esters are possible. They result from modification of
the fatty group, modification of the hydroxy compound or both. This
chemistry is well understood and the platform from which new technology
can be launched.
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- Complex esters in addition to being of interest themselves, have been
found to have very interesting interactions with alkyl silicones
resulting in modification of wetting, spreading, viscosity and gel
formation. These very properties are of extreme interest to cosmetic
formulators.
- The CosmoSurf line of esters include the complex esters and alkyl
silicone modifications which allow the formulator new flexibility in
making products.
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- Organo-functional silicone compounds are amphillic materials. That is
they have an oil soluble group and a silicone soluble group on the same
molecule. While both groups are hydrophobic (water hating) they are not
soluble as pure materials in each other, Oil soluble groups are
oleophilic and silicone groups are siliphilic.
- Alkyl silicones are soluble in esters. That is they form clear
solutions. Despite this clarity, the concentration of the silicone is
highest at the surface and in micelles. It is exactly this behavior that
allows for the modification of esters by adding specific alkyl silicone
compounds.
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- Alkyl dimethicone compounds conform to the following structure:
- CH3 CH3 CH3 CH3
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- CH3-Si-(-
O—Si-)a—(O-Si -)b-O-Si-CH3
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- CH3 CH3 (CH2)c CH3
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CH3
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- They contain silicone groups (red) and alkyl groups (green).
- CH3 CH3 CH3 CH3
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- CH3-Si-(-
O—Si-)a—(O-Si -)b-O-Si-CH3
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- CH3 CH3 (CH2)17 CH3
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CH3
- It is this dichotomy that makes them amphillic and of interest in
modifying esters.
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- Alkyl Dimethicone compounds added at below their CMC
- Lower surface tension
- Imporve Slip
- Improve play time
- Improve spreadability
- Alkyl Dimethicone compounds added at their CMC
- Begin to form micelles
- Increase viscosity
- Increase play time
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- Alkyl Dimethicone compounds added at at higher levels
- Provide gels
- Liquify under pressure
- Provide outstanding aesthetics.
- Alkyl Dimethicone compounds offer a wide range of attributes.
- Raw materials are known and registered
- Ratios offer formulator maximum flexibility.
- Ability to alter chemistry of silicone and ester offers possibility for
unique products.
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- Clear low viscosity water-white Liquid
- Dry Ester
- Good Spread
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- Gel soft feel
- Outstanding flow
- Good Cushion
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- For More Information contact:
- Kevin@surfatech.com
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